Prof. V.W.W. Yam　　　任詠華教授

B.Sc., Ph.D. H.K.;
Member of Chinese Academy of Sciences (China);
Fellow of TWAS, The Academy of
Sciences for the Developing World;
CSci; C.Chem.; F.R.S.C.; Chair of Chemistry;
Philip Wong Wilson Wong Professor
in Chemistry and Energy

  
   
                   

Office:

Prof. V. W. W. Yam

Room 504
Chong Yuet Ming Chemistry Building
The University of Hong Kong
Pokfulam Road
Hong Kong

          
  Tel. No.:
E-Mail:
 (852) 2859 2153
wwyam@hku.hk
         
Research Interests            
           
   
The major focus of our research is on the molecular design and synthesis of novel inorganic/organometallic metal complexes that may find potential applications as functional metal-based molecular materials. Of particular interest are luminescent polynuclear metal complexes that show weak metal-metal interactions and luminescent metal complex and supramolecular systems of charge-transfer excited states, with d6, d8 or d10 metal centres, in particular those containing alkynyl, chalcogenido, chalcogenolato, pnictogenido and polypyridyl ligands. Through the systematic study of the electronic spectroscopy of the newly synthesized metal complex systems, a fundamental understanding of the spectroscopic and luminescence origin as well as the structure-property relationship of these complexes could be established. Apart from their fundamental spectroscopic, mechanistic, electrochemical, photoluminescence (PL), and photochemical studies, attempts will be made to explore their potential applications as functional molecular materials in the following areas:

Optoelectronic Materials

The exploration of triplet emitters for electroluminescence (EL) applications has attracted immense interest. The project involves the design and synthesis of novel metal-based molecular triplet emitters as the emissive layer for the fabrication of high-efficiency organic light-emitting diodes (OLEDs). The emission colours could be readily tuned through a systematic variation of the nature of the metal centre and its ancillary ligands. Molecular materials for other optoelectronic applications will also be explored.

Spectrochemical and Luminescence Chemosensors and Biolabels

The project involves the design and synthesis of luminescent metal complexes capable of showing selective binding and molecular recognition properties to substrates of environmental and biological interests, such as ions, volatile organic compounds (VOCs), oxygen, gases and vapours, solvents, DNA and proteins, which could be accomplished through the incorporation of various functional ligands such as those containing macrocycles and calixarene-type receptor sites. Extension of the work will also be made to design molecular materials as probes for changes in temperature and the microenvironment.

Photochromic and Photoswitching Materials

The project involves the design and synthesis of metal complexes capable of exhibiting photochromic and photoswitching behaviour via photoinduced trans-cis isomerization or ring-opening/closing processes, which may find applications in optical switches, memory and storage. Intramolecular sensitization of the photochromic and photoswitching moieties by the metal complex chromophore will be explored.

Molecular Electronics

The project involves the study of the electronic communication between metal centres across alkynyl bridges of our newly synthesized luminescent carbon-rich rigid-rod and hyperbranched metal alkynyl systems and their possible utilization as building blocks for molecular wires and junctions based on the intriguing electron delocalization properties and the molecular rigidity of the alkynyl unit.

Nonlinear Optical (NLO) and Mesoporous Materials

The project involves the design and synthesis of donor-acceptor type unsymmetrical metal alkynyl and metal surfactant complexes with second harmonic generation (SHG) properties. Incorporation of metal surfactant complexes into monolayers and Langmuir-Blodgett (LB) films will be made to produce SHG films. The exploitation of metal surfactant complexes for the template synthesis of mesoporous materials that may find applications in catalysis and optical sensing will also be made.

Nanoclusters and Nanomaterials

The project involves the design and synthesis of metal chalcogenido, chalcogenolato, and pnictogenido clusters of various nuclearity and the study of their optical properties. The exploitation of these clusters as single-source molecular precursors for the synthesis of nanoparticles that may have interesting semiconducting and optical properties will be made. The controlled template-directed synthesis of nanomaterials will also be made.

  
   
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Selected Publications
      
           
   
  1. C. Yu, K.H.Y. Chan, K.M.C. Wong, V.W.W. Yam, Proc. Natl. Acad. Sci. USA, 2006, 103, 19652.
  2. V.W.W. Yam, K.H.Y. Chan, K.M.C. Wong, B.W.K. Chu, Angew. Chem. Int. Ed., 2006, 45, 6169.
  3. H.S. Lo, S.K. Yip, K.M.C. Wong, N. Zhu, V.W.W. Yam, Organometallics, 2006, 25, 3537.
  4. M.J. Li, B.W.K. Chu, V.W.W. Yam, Chem. Eur. J., 2006, 12, 3528.
  5. V.W.W. Yam, K.M.C. Wong, L.L. Hung, N. Zhu, Angew. Chem. Int. Ed., 2005, 44, 3107.
  6. S.K. Yip, E.C.C. Cheng, L.H. Yuan, N. Zhu, V.W.W. Yam, Angew. Chem. Int. Ed., 2004, 43, 4954.
  7. V.W.W. Yam, C.C. Ko, N. Zhu, J. Am. Chem. Soc., 2004, 126, 12734.
  8. D.B. Yu, V.W.W. Yam, J. Am. Chem. Soc., 2004, 126, 13200.
  9. V.W.W. Yam, X.X. Lu, C.C. Ko, Angew. Chem. Int. Ed., 2003, 42, 3385.
  10. V.W.W. Yam, Acc. Chem. Res., 2002, 35, 555.
  11. V.W.W. Yam, B. Li, N. Zhu, Adv. Mater., 2002, 14, 719.
  12. V.W.W. Yam, K.M.C. Wong, N. Zhu, J. Am. Chem. Soc., 2002, 124, 6506.
  13. V.W.W. Yam, E.C.C. Cheng, N. Zhu, Angew. Chem. Int. Ed., 2001, 40, 1763.
  
   
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